2-ETHYLHEXYL ACRYLATE

Acrylic ester used for polymer manufacturing and as a raw material for syntheses.

Molar Mass(g/mol): 184.28

Chemical formula:



Stoichiometric formula: C11H20O2  

CAS number: 103-11-7



Technical Informations

Application Advice/Typical Applications

2-ethylhexyl acrylate is used primarily for manufacturing homopolymers and copolymers. 2-ethylhexyl acrylate can be copolymerized for instance with acrylic acid and its salts, esters and acrylamide, with methacrylic acid, methacrylates, acrylonitrile, styrene, maleic acid esters, vinyl acetate, vinyl chloride, butadiene, unsaturated polyesters etc. 2-ethylhexyl acrylate is an important raw material and a starting material for many chemical syntheses.

Parameter Value, Unit
Appearance, form Transparent, colorless, clear liquid
Odor Characteristic, pungent
Boiling point 216 °C
Melting point -90 °C
Vapour pressure at 0°C 0.002 kPa
Vapour pressure at 20°C 0.016 kPa
Vapour pressure at 50°C 0.133 kPa
Flash point (Closed cup) 82 – 87 °C
Flash point (Open cup) 92 °C
Explosion limit – upper at 126  °C 6.0 % v/v
Autoignition temperature 258 °C
Heat of evaporation at boiling point 234 kJ / kg
Heat of polymerization 332 kJ / kg
Heat of combustion 33755 kJ / kg
Specific heat of liquid at 20°C 1.97 kJ / kg.K
Density of liquid at 20°C 886 kg / m3
Vapour density (air=1) 6.4
Coefficient of cubic expansion 0.8 × 10-3
Refractive index at 20°C 1.434 – 1.437
Viscosity at 0°C 2.79 mPa.s
Viscosity at 20°C 1.82 mPa.s
Surface tension at 20°C 21 mN / m
Solubility ester in water 9.6 mg / l
Solubility water in ester 15 mg / l
Electrical conductivity 2.8 × 103 pS / m




Shipping and Storage

2-ethylhexyl acrylate is transported in specially equipped railway cars or tanker trucks.
Transport containers are filled to a maximum of 94% of their capacity.


In order to prevent spontaneous polymerization, 2-ethylhexyl acrylate must always be stored under air, never under inert gases. The air (oxygen presence is required for a proper functionality of the stabilizer. Product storage temperature must not exceed 35°C. Under these conditions, a storage stability of one year can be expected.

It is advisable to minimize the likelihood of 2-ethylhexyl acrylate overstorage by a strict observance of the “first-in-first-out” storage principle. For storage periods extended over one month, it is advisable to replenish the dissolved oxygen content in the product by suitable aeration.
Stainless steel or aluminium is the recommended material for storage tanks and piping. Even though 2-ethylhexyl acrylate does not corrode carbon steel, there is a risk of product contamination if corrosion occurs. All metal made equipment (tanks, pumps, piping etc.) must be earthed.
All national laws and directives, as well as local regulations governing storage, handling, distribution and disposal of flammable liquids must be strictly observed. Avoid exposure to high temperatures, sparks, flame, light and frost. Keep separated from oxidizing materials. Keep the container tightly closed. For additional detailed information see the brochure „SAFE HANDLING AND STORAGE OF ACRYLIC ESTERS“, issued by the European Basic Acrylic Monomers Manufacturers Association (EBAM).



Product Security/Health and Safety

Please refer to the Safety Data Sheet for safety information. 





For further information regarding this product please refer to:

Synthomer MDP,
Phone:
FAX:
eMail: 4information@synthomer.com


Properties

Character Value Unit
2-ethylhexyl acrylate min. 99.5
Alcohols max. 0.08
2-ethylhexyl acetate max. 0.2
2-ethylhexyl propionate max. 0.2
Other organic impurities max. 0.3
Color max. 10 APHA 
Water max. 0.04
Inhibitor (MEHQ) * 0.001 - 0.002
Acidity (as Acrylic acid) max. 0.009
Appearance Clear, colorless liquid
Refractive index ** 1.434 – 1.437


Available Documents

Technical datasheet


© 2018 Synthomer plc